Randy and Howard are psyched to rock out with pop star Levander Hart, but they are unaware that Levander is secretly plotting his revenge for being kicked out of their band.
- The title is based on the song "Unchain My Heart" by Ray Charles (and covered by the Rivingtons, Trini Lopez, Joe Cocker, the Bobs, George Williams, and others) or possibly the song "Un-Break My Heart" by Toni Braxton.
- Blue Stank is introduced in this episode.
- Running Gag: Howard criticizing Randy's counting.
- 30 Seconds to Math returns for the first time in season 2.
- Howard's hair resembles Super Saiyan, from anime Dragon Ball.
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