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Penn Zero obtained the job as part-time hero when his parents, Brock and Vonnie Zero, found themselves trapped in the "Most Dangerous World Imaginable", with no way to escape but enough experience to stay alive. From then on, he lived with his Aunt Rose and Uncle Chuck, and could communicate with his parents via the Multi Universe Hologram Uplink (MUHU). As a part-time hero working for Phyllis, he is joined by his best school friends Boone and Sashi to hop through dimensions using the Multi Universe Transprojector to foil the plans of his art teacher Rippen and the Principal Larry.
His best friend.
In Rip-Penn, Penn loses his temper larry taking about pinwheel story.
- In Lady Starblaster revealed that Penn is a talented dancer.
- In "Zap One", it's revealed that he initially wore a blue-green sweater before he had his trademark shirt and fake chain mail mesh, which were gifts that he found from his parents after his first mission. Moreover, his MUHU was also a gift from them.