Phil makes his second appearance and makes his first speaking role.
When in bed, Rippen has his stuffed poodle Freddy with him, the poodle being revealed in "The Princess Most Fair".
For the first time, a part-time work character changes roles, Larry becoming the part-time villain, with Rippen having to become the part-time minion later on.
The title references the Roman Catholic prayer, the "Ave, Maria" or "Hail, Mary." addressed to the mother of Jesus.
This is the first time where Rippen did not wear his normal outfit.
Penn Zero: Part-Time Hero (Opening Theme) • We're Breaking Out of Here for Christmas • Time to Kill • We Can Catch the Milkman • What is a Princess? • Pigoilet • Victory is Mine at Last • The Truth of It Is • Moonlight Bright • This is a Real Song • Boone Reads On • Race to the Top • Race to the Top (reprise) • You're a Karaoke King • High in the Sky • Breath In, Breath Out • Bad Weed • Today's The Day • My Name is Penn Zero • Save the Worlds • In the Splishy Splashy Sea • Come Aboard with Me • Training to Win • Wings of Destiny Song • Sometimes We Need a Friend • Build and Backup Now • The Time Table • Everybody Chillax • Why Won't You Turn Green • It's the Best Friend Song • It's the Best Friend Make Up Song • Grinkon's Song • Its Not Just Today
Middleburg • Middleburg Central High • The Odyssey • Fish Stick on a Stick • North Pole • Knight World • Superhero World • Arabian World • Plush Toy World • Clown World • Dinosaur Cowboy World • Cereal World • Old English World • Giant Monster World • Zombie World • Space World • Ocean World • Color World • Musical Fairy Tale World • Caveman Spy World • Future Barbarian World • Ultrahyperball World • Demon World • Alien World • Galaxy World • Temple World • Dragon World • Gothic Mystery World • Plant World • Animal Barbarian World • Toy World • Outer Space Court World • Robot World • Pirate World • Fairymania World • Steampunk World • Ball World • Ghost World • Rock, Paper, Scissor World • Beast World • Anime World • Sitcom World • Nothingness • Most Dangerous World Imaginable • Least Dangerous World Imaginable
Objects
Multi-Universe Hologram Uplink • Multi-Universe Transprojector • Pigoilet • The QPC Unit • Vortex Tops • Specs