These are villains in live-action films and television shows.
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A
- A.J. Arno
- Aadam
- Abdullah
- Absorbing Man
- The Aceys
- Candace Adams
- Amber Addison
- Aerosol
- Agatha (Jessie)
- Agatha Harkness
- Agent 33
- Agent Gordon (Parallel Universe)
- Lope de Aguirre
- Aida
- Alecto
- Alex (Halloweentown)
- Amber Algoode
- Algrim
- Alioth
- Allegiant General Pryde
- The Alligator
- Alonzo
- Alucard Van Heusen
- Amber Lee Adams
- The Ambusher
- Ammit
- Amy Madden
- Andrea Sage
- André (dinosaur)
- Angar the Screamer
- Angela (Jessie)
- Angelica Teach
- Angelo (Who Framed Roger Rabbit)
- Brooke Angels
- Anita Lucas
- Mary Ann (Pair of Kings)
- Anna and Fontana
- The Annihilator
- Apaches
- Appoline
- Arthur Harrow
- Artie Smalls
- Hamish Ascot
- Ashcan and Pete
- Mr. Ashland
- Lucian Aster
- AT-AT drivers
- Auctioneer (Pirates of the Caribbean)
- Audrey (Descendants)
- Aunt Spiker
- Aunt Sponge
- Axel (Jessie)
- Thomas Ayerton
- Ayesha
B
- Big Bad Wolf
- Dominic Badguy
- Sunil Bakshi
- Marta Balatico
- The Bandits
- Banshee (Darby O'Gill and the Little People)
- Hector Barbossa
- Barnaby (Babes in Toyland)
- Bucky Barnes
- Chelsea Barnes
- Baron Strucker
- Baroness Von Hellman
- Dr. Simon BarSinister
- Rubin Bartlett
- Elton Bates
- Batroc
- Battle Droids
- Baylan Skoll
- BB-9E
- Beauty Smith
- Cutler Beckett
- Dr. Addison Bennet
- Bennett (Sonny with a Chance)
- Beowulf
- Bernardo Vasquez
- Bernice
- Bianca
- Billie Pearce
- Birdzilla (Homeward Bound)
- Black Fairy
- The Black Falcon
- Black Mariah
- Black Order
- Black Scorpions
- Blackbeard
- Blackbeard's Zombie Officers
- Agent Felix Blake
- Meredith Blake
- Blind Witch
- Bloodbottler
- Blue Tornado
- Bo'sun
- Boastful Loki
- Bobo the Bear
- Aristotle Bolt
- Bonecruncher
- Bookman
- Borg Guillarson
- Inspector Bouchet
- Brace Channing
- Brad Wolfe
- Ellen Brandt
- Leet Brannis
- Brenda (Raven's Home)
- Brian
- Briar Cudgeon
- Bride of Nine Spiders
- Bridget (Mighty Med)
- Brooke
- Bruno von Stickle
- Josh Bryant
- Bryn Breitbart
- Buck Willingham
- Buldeo (Rudyard Kipling's The Jungle Book)
- Bullseye (Marvel)
- Henry Burke
- Bushmaster
- Butcherboy
C
- Cad Bane
- CALLIE
- Calliope
- Ian Calloway
- Marco Campbell
- Big Boy Caprice
- Captain (Lab Rats)
- Captain Hook
- Captain Jay Fuller
- Captain Nemo
- Captain Phasma
- Captain Rochefort
- Mr. Carruthers
- Carter and Trygstad
- Sharon Carter
-
- Castor
- Monty Cathcart
- Cattlemen
- Theo Cavenaugh
- Cavendish's Gang
- Butch Cavendish
-
- Chad (Gamer's Guide)
- Chainsaw
- Charlotte (Jungle 2 Jungle)
- Chad Charming
- Chase Henderson
- Chaz
- Cheri
- Rhoda Chesterfield
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- Chimera (Percy Jackson and the Olympians)
- Chino
- Chitauri
- Christian Ward
- Chucky Albertson
- Cinderella's Stepmother
- Clandestines
- Clanker
- Dr. Claw
- Mrs. Clegg
- Clone Troopers
- CLU 2.0
- Clueless Morgan
- Coach Barker
- Coach Penny
- Coach Pramod Kadam
- Coach Wilson
- The Coachman
- Colby Madden
- Latham Cole
- Dr. Elliot Coleye
- Collector
- Mr. Collinsworth
- Colonel Heller
- Colonel Pierson
- Colonel Weber
- Mr. Condor
- James Conroy
- Constantine
- Cookie
- Mr. Corelli
- Corvus Glaive
- Cottonmouth
- Coven of the Eight
- Crash (Pirates of the Caribbean)
- The Crew of the Black Pearl
- The Crew of the Flying Dutchman
- Crew of the Silent Mary
- The Crew of the Wicked Wench
- Criminal
- Wilson Croft
- Darren Cross
- Crossbones
- Stan Cruge
- Lisa Cucuy