Captain Super Captain is the fundamental superhero: powerful, brave, and booming with a slight ego. Though he is overconfident with his superpowers, he does learn to acknowledge that his non-super talents can also make him a hero, thanks to Penn. He also appears to have a strong degree of care for allies and relatives whether they be mind-controlled or simply evil, as he often implores them to be good rather than directly fight them. Much to the irritation of everyone else, Captain Super Captain has a habit of taking time to announce his name in a bombastic manner.
Penn Zero: Part-Time Hero (Opening Theme) | We're Breaking Out of Here for Christmas | Time to Kill | We Can Catch the Milkman | What is a Princess? | Pigoilet | Victory is Mine at Last | The Truth of It Is | Moonlight Bright | This is a Real Song | Boone Reads On | Race to the Top | Race to the Top (reprise) | You're a Karaoke King | High in the Sky | Breath In, Breath Out | Bad Weed | Today is the Day | My Name is Penn Zero | Save the Worlds
Middleburg | Middleburg Central High | The Odyssey | Fish Stick on a Stick | Knight World | North Pole | Superhero World | Arabian World | Plush Toy World | Chuckle City | Big Butte | Space World | Ocean World | Musical Fairy Tale World | Caveman Spy World | Alien World | Dragon Flight School | Plantywood | Most Dangerous World Imaginable | Least Dangerous World Imaginable
Multi-Universe Hologram Uplink | Multi-Universe Transprojector | Pigoilet | The QPC Unit | Vortex Tops | Specs